Your router is running at 192.168.100.1. Did you change it to this address. The default address is 192.168.1.1.
If you run PPPoE on the modem and DHCP on the router you run two routers chained. As long as it works for you it is O.K. to run it. You must be aware of this setup, however, when you need special services. For instance port forwardings must be setup on the modem and router in this case. A Dynamic DNS service must be setup on the modem and not the router. Bandwitdh may also suffer a bit because you are running through two routers and two network address translations. That's why it is usally better to use only one router (instead of two at the moment: your modem running as router as well as the WRT as router).
I would recommend to use the PPPoE on the router and the modem in bridge mode. If you cannot get it running this way (with the help from someone in the modem forum perhaps) then you could also ask the ISP. Maybe they register the hardware MAC address of the device connected and don't accept connections from other devices. You could try the MAC clone function on the WRT to clone the MAC address of the modem. Maybe then the WRT is able to connect with PPPoE through the bridged modem.
Could you check the status page on the WRT when you have set it up for PPPoE? There should be a connect button. Press it and look what error message you get. This may reveal what the problem is.
An alternative might be to use your modem as modem/router and setup the WRT as access point. You could follow the steps in
this post. The modem/router would be the first router and the WRT is the second. With this setup you have only one operating router (your modem/router) instead of two making administration easier. But again, this is not necessary if everything works and you are happy as it is. The most important thing is that you have your broadband internet connection up and running.